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Additional info for Dictionary of Carbohydrates
Zero in MeOH). Me glycoside, tri-Ac: Methyl 4-acetamido2,3-di-O-acetyl-4,6-dideoxy-a-L-mannopyranoside C13H21NO7 303. 311 Cryst. (Et2O/pentane). Mp 160-1618. [a]D -94 (c, 1. zero in MeOH). [26552-82-9] Lee, C. H. et al. , Tet. Lett. , 1966, 5837 (isol, struct, D-N-Ac, a-D-Me pyr) Brimacombe, J. S. et al. , J. C. S. (C) , 1969, 1270 (a-L-Me pyr, a-L-Me pyr tri-Ac) Stevens, C. L. et al. , J. A. C. S. , 1970, ninety two, 3160 (a-D-Me pyr, a-D-Me pyr N-Ac, a-D-Me pyr tri-Ac) Caroff, M. et al. , Eur. J. Biol. , 1984, 139, 195 (occur) Eis, M. J. et al. , Carbohydr. Res. , 1988, 176, 316 (D-form, ! synth, a-D-Me pyr, pmr) Kenne, L. et al. , J. C. S. Perkin 1 , 1988, 1183 (a-D-Me pyr, a-D-Me pyr N-Ac, pmr) Ito, T. et al. , Carbohydr. Res. , 1994, 256, 113 (2-O-Methylperosamine) A-409 4-Amino-4,6-dideoxy-3-C methylmannose A-409 2-Amino-1,2-dideoxy-1-nitromannitol / A-411 A-410 CH 2NO2 CH three O OH OH H 2N Á H 2N HO α−D−Pyranose−form OH OH OH CH 2OH CH three C7H15NO4 177. 2 D-form N-Me: 4,6-Dideoxy-3-C-methyl-4-(methylamino)-D-mannose. Sibirosamine [35665-47-5] Constit. of Sibiromycin, S-39. Struct. revised in 1982. a-D-Pyranose-form Me glycoside, N-Me: Methyl 4,6-dideoxy3-C-methyl-4-(methylamino)-a-D-mannopyranoside [49754-58-7] C9H19NO4 205. 253 Cryst. (as hydrochloride). Mp 184-1878. [a]20 D -50 (in H2O). b-D-Pyranose-form Me glycoside, N-Me: Methyl 4,6-dideoxy3-C-methyl-4-(methylamino)-b-D-mannopyranoside C9H19NO4 205. 253 Amorph. (as hydrochloride). Mp 1781798. [a]20 D +75 (H2O). Me glycoside, N-Me, N-Ac: [49754-59-8] C11H21NO5 247. 291 Mp 125-1268. [a]20 D -121 (c, zero. three in MeOH). Me glycoside, N-Me, N,2-di-Ac: [4981299-9] C13H23NO6 289. 328 Mp 135-1368. [a]20 D -70 (c, zero. four in MeOH). Me glycoside, N,2,3-tri-Ac: C15H25NO7 331. 365 Mp 127-1288. [a]20 D -25 (c, zero. three in MeOH). L-form 2-Me: 4,6-Dideoxy-3-C-methyl-2-Omethyl-L-mannose. Kansosamine [115374-44-2] C8H17NO4 191. 227 Residue found in lipooligopolysaccharides of Mycobacterium kansasii . 2-Me, N-(2-methoxypropanoyl): N-Acylkansosamine [101978-82-9] [92355-88-9] C12H23NO6 277. 317 Isol. from lipooligosaccharides of Mycobacterium kansasii . Sol. H2O. [a]24 D +14. seventy three (c, zero. 019 in H2O). Mesentsev, A. S. et al. , Tet. Lett. , 1973, 2225 (synth, pmr, derivs) Parker, okay. A. et al. , Tet. Lett. , 1982, 23, 1763 (struct) Hunter, S. W. et al. , J. Biol. Chem. , 1984, 259, 9729 (Kansosamine, N-acylkansosamine) Yoshimura, J. et al. , Carbohydr. Res. , 1987, 166, 253 (synth) Giuliano, R. M. et al. , Carbohydr. Res. , 1988, 183, 277 (synth) 89 C6H14N2O6 210. 186 D-form N-Ac: 2-Acetamido-1,2-dideoxy-1-nitromannitol [14199-86-1] C8H16N2O7 252. 224 Cryst. (EtOH). Mp 172-1738. [a]25 D -16. eight (c, 2. four in H2O). Sowden, J. C. et al. , J. A. C. S. , 1960, eighty two, 2303 (synth) Sowden, J. C. et al. , equipment Carbohydr. Chem. , 1962, 1, 235 (synth) 2-Amino-2,4-dideoxy-erythro pentose O HO A-411 α-D-Pyranose-form OH NH2 C5H11NO3 133. 147 a-DL-Pyranose-form Me glycoside: Methyl 2-amino-2,4-dideoxy-a-DL-erythro-pentopyranoside [82753-62-6] C6H13NO3 147. 174 Cryst. (EtOH) (as hydrochloride). Mp 2138 (hydrochloride). CAS no. refers to hydrochloride. Me glycosides, N-Ac: Methyl 2-acetamido2,4-dideoxy-a-DL-erythro-pentopyranoside [82753-72-8] C8H15NO4 189.