By Rüdiger Memming
Semiconductor electrochemistry offers with many facets, starting from primary semiconductor physics to advanced results, reminiscent of cost move procedures at semiconductor-liquid surfaces or photoreactions at semiconductor debris. Its purposes disguise very important fields of current and destiny expertise together with solar power conversion or semiconductor equipment expertise, micromachining, and nanotechnology.
Providing either an creation and an up to date survey to the entire box, this article captivates via its transparent variety and encouraging, but sturdy presentation. Rüdger Memming, an said specialist, basically addresses actual chemists
and electrochemists, yet fabrics scientists, physicists, and engineers facing semiconductor expertise and its functions also will gain vastly from this article.
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Additional resources for Semiconductor Electrochemistry (Wiley-Vch)
Forty eight Potentials and Thermodynamics of Electrochemical Cells . . . . . . . . SO Chemical and Electrochemical Potentials . . . . . . . . . . . . . . . . . 50 mobile Voltages . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . fifty three Reference Potentials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . fifty five usual power and Fermi point of Redox platforms . . . . . . . . . fifty six four four. 1 four. 2 four. 2. 1 four. 2. 2 four. 2. three four. 2. four four. three four. four Experimental innovations . . . . . . . . . . . . . . . . . . . . . . . . . . Electrode training . . . . . . . . . . . . . . . . . . . . . . . . . . . . Current-Voltage Measurements . . . . . . . . . . . . . . . . . . . . . . Voltametry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Photocurrent Measurements . . . . . . . . . . . . . . . . . . . . . . . . Rotating Ring Disc Electrodes . . . . . . . . . . . . . . . . . . . . . . . Scanning Electrochemical Microscopy (SECM) . . . . . . . . . . . . . . Measurements of floor Recombination and Minority service Injection ImpedanceMeasurements . . . . . . . . . . . . . . . . . . . . . . . . . . sixty one sixty one sixty one sixty one sixty three sixty three sixty four sixty five sixty seven VIII Contents four. four. 1 four. four. 2 four. five four. 6 four. 7 four. 7. 1 four. 7. 2 simple principles and strategies . . . . . . . . . . . . . . . . . . . . . . . . . evaluate of Impedance Spectra . . . . . . . . . . . . . . . . . . . . . . Intensity-Modulated Photocurrent Spectroscopy (IMPS) . . . . . . . . Flash Photolysis Investigations . . . . . . . . . . . . . . . . . . . . . . . floor technological know-how recommendations . . . . . . . . . . . . . . . . . . . . . . . . . Spectroscopic tools . . . . . . . . . . . . . . . . . . . . . . . . . . . . In Situ floor Microscopy (STM and AFM) . . . . . . . . . . . . . . . sixty seven sixty nine seventy four seventy five seventy six seventy six seventy eight five five. 1 five. 2 five. 2. 1 five. 2. 2 five. 2. three five. 2. four five. three five. three. 1 five. three. 2 five. three. three five. three. four five. three. five Sokid-Liquid lnterface . . . . . . . . . . . . . . . . . . . . . . . . . . . . constitution of the Interface and Adsorption . . . . . . . . . . . . . . . . . cost and capability Distribution on the Interface . . . . . . . . . . . . The Helmholtz Double Layer . . . . . . . . . . . . . . . . . . . . . . . . The Gouy Layer within the Electrolyte . . . . . . . . . . . . . . . . . . . . . the gap cost Layer within the Semiconductor . . . . . . . . . . . . . . cost Distribution in floor States . . . . . . . . . . . . . . . . . . . research of the aptitude Distribution . . . . . . . . . . . . . . . . . . . Germanium Electrodes . . . . . . . . . . . . . . . . . . . . . . . . . . . Silicon Electrodes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Compound Semiconductor Electrodes . . . . . . . . . . . . . . . . . . . Flatband strength and place of power Bands on the Interface . . . Unpinning of strength Bands in the course of Illumination . . . . . . . . . . . . . eighty one eighty one eighty three eighty three eighty five 86 ninety two ninety three ninety three ninety nine a hundred 102 107 6 6. 1 6. 1. 1 6. 1. 2 6. 1. three 6. 1. four 6. 2 6. 2. 1 6. 2. 2 6. three 6. three. 1 6. three. 2 6. three. three 6. four 6. five Electron move Theories . . . . . . . . . . . . . . . . . . . . . . . . . the idea of Marcus . . . . . . . . . . . . . . . . . . . . . . . . . . . . Electron move in Homogeneous recommendations . . . . . . . . . . . . . . . The Reorganization strength . . . . . . . . . . . . . . . . . . . . . . . . . Adiabatic and Non-adiabatic Reactions . . . . . . . . . . . . . . . . . . Electron move procedures at Electrodes . . . . . . . . . . . . . . . . . The Gerischer version . . . . . . . . . . . . . . . . . . . . . . . . . . . . . power States in resolution . . . . . . . . . . . . . . . . . . . . . . . . . . Electron move . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Quantum Mechanical remedies of Electron move techniques . . . Introductory reviews . . . . . . . . . . . . . . . . . . . . . . . . . . . Non-adiabatic Reactions . . . . . . . . . . . . . . . . . . . . . . . . . . . Adiabatic Reactions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . the matter of Deriving price Constants . . . . . . . . . . . . . . . . . comparability of Theories . . . . . . . . . . . . . .